‘Ring Fit Adventure’ Is a Nintendo Switch Exercise RPGGeek Pick: Withings Move Is an Intro to Fitness Wearables Here’s a fun fact from me, your good friend who loves to ruin the things you love: You know that legendary scene in The Avengers where Nick Fury approaches Captain America in a grimy boxing gym? The scene where Cap is basically working through a powder keg of PTSD on a heavy bag, and then punches it clean off the hook? Man, what a great scene that is, but it’s immediately ruined if you know anything about boxing. Dude’s form is so bad, y’all. His stance is all wrong and his feet seem to be planted when he should be on his toes, moving way looser, and punching from his legs and hips, not shoulders.It’s fine. It’s a big, loud superhero movie, I’m not here to say it’s a bad movie because Chris Evans didn’t learn to move like Anthony Joshua before filming. Plus, everything turned out fine by the time Captain America: The Winter Soldier came around. The Russo Brothers are at their best when filming tight, close-quarters fight sequences and the martial arts on display in that movie are exceptional. Evans’ martial arts abilities had skyrocketed by then and he even takes on a villain (WHERE MY BATROC CREW AT?!) played by UFC legend (and recent retiree) Georges St. Pierre. St. Pierre is a legend of the Octagon and a longtime user of Hayabusa fight gear.Does this seem like it’s going nowhere? Don’t worry, I’m about to bring it full-circle like the LOST finale. This week, Hayabusa has announced a partnership with Marvel to create top-of-the-line fight gear inspired by some of the greatest superheroes in the world. St. Pierre, both a legendary fighter and an MCU alum is, appropriate, the spokesman for the line. The Marvel Hero Elite Series is now available for preorder.The best boxing gloves in any universe are here.Begin your origin story.Limited edition. Pre-order today. https://t.co/alrshMd1Dp pic.twitter.com/9XqdnD1UVe— Hayabusa (@hayabusacombat) February 19, 2019Hayabusa’s first wave of Marvel gear is largely glove-centric, featuring a number of new colorways and iterations of their current T3 model. First, a bit about the T3 (which is, for the record, my go-to glove for boxing and Muay Thai): these gloves are made from a synthetic leather and come in a variety of sizes. Their most notable feature is the double-wristlock strap system, which features two wrist straps that overlay to provide some of the best wrist support in the game. This is crucial and will pay off if you’re a longtime martial artist or if you’re just getting started and your wrists haven’t acclimated to hitting a heavy bag yet. The gloves are durable as heck and hold up great through bag work, mitt work, and sparring alike.The real draw here though is the different colorways. The first wave features gloves inspired by Captain America, Iron Man, Captain Marvel, Black Panther, and The Punisher. These aren’t subtle homages, either. The Cap gloves feature big, loud imprints of his classic shield while the Captain Marvel gloves feature the emblem made famous by Jamie McKelvie’s redesign of Carol Danvers’ costume. Black Panther’s look like a natural extension of his vibranium armor and each of the gloves on The Punisher’s feature half of his logo, forming the whole thing when you hold them together.Hayabusa Limited Edition Marvel Hero Elite Series Captain America Boxing Gloves (Photo Credit: Hayabusa)The line also features Brazilian jiu-jitsu Punisher gear, including rash guards, fight shorts, and a gi. There aren’t currently any other superheroes lined up for the BJJ category but I’ve got a feeling that’ll change if these do well — which they’re going to, by the way.These are some of the coolest boxing gloves and pieces of fight gear you’re likely to come across today. The price tag on the gloves may seem a bit high for those looking to get into training but personally, I’d advise that boxing gloves are meant to keep you from hurting yourself and the people around you. The T3 is absolutely worth the price tag alone and these happen to come with way cooler paint jobs than you’ll find in any other boxing line.Hayabusa Limited Edition Marvel Hero Elite Series Punisher Rash Guard (Photo Credit: Hayabusa)A big goal of the Hero Elite initiative is to encourage fans of the world of Marvel to begin their own “origin story” through fitness. I’m sure I don’t need to tell y’all that exercise and hitting the gym is the first step in a happier and healthier life and hey, personally, I’ll attest to boxing being one of the best forms of it. I’m no fitness savant — I’m a guy who spends most of his day at his desk writing about movies and comics. But boxing every week over the last couple of years has helped me mitigate stress and anxiety and gotten me in better shape than I’ve ever been. Plus it’s fun to watch MCU movies and now be able to recognize when certain disciplines or techniques are utilized (I yelped when Thanos threw a legit Muay Thai knee when fighting the Hulk in Infinity War). It is, sorry to utilize a cliche, the best way to feel like a superhero.That you can now feel like a superhero at boxing class and look the part too is incredibly rad. Don’t miss out on the Hayabusa Marvel Hero Elite Series.More on Geek.com:7 Sneakers Your Favorite DC Superhero Would WearBest Nerdy Fitness Gear to Rep Your Fandom at the Gym10 Best Geeky Sneakers of 2018 Stay on target
Facebook Twitter Google+LinkedInPinterestWhatsAppBahamas, July 31, 2017 – Nassau – A number of members of Team Bahamas enjoyed a motorcade through parts of New Providence, on July 26, 2017, to celebrate their multi-medal-winning performance at the recent Commonwealth Youth Games that were held in The Bahamas, July 18-23. The Bahamas won 13 medals, including one gold medal, and placed 16th in a field of 64 countries taking part in the event.(BIS Photos/Eric Rose) Related Items: Facebook Twitter Google+LinkedInPinterestWhatsApp
UK HR software provider CIPHR has appointed Claire Williams as head of people.In her new role, Williams will oversee the development of the organisation’s HR function, with a specific focus on organisational culture, talent management and learning and development.Williams joined CIPHR in March 2018 as a senior HR systems consultant, leading a review into the organisation’s consultancy offering to clients. She will head up CIPHR’s strategic HR consultancy function alongside her role as head of people.Williams has more than 12 years’ experience in HR, both in-house and in consultancy roles, including at publisher Parragon Books and fine wine storage organisation Octavian. She also ran her own HR firm, Ten to Five Consultancy, for three years, and worked as a consultant at CitrusHR.
When it comes to criticizing these young dancers, Lythgoe said they can handle it. “These kids are so accustomed to competitions, it’s almost easier to judge them and give them quite harsh criticisms, too,” he said. “They take it really well.”Miami native Gaby Diaz, 19, won last year’s season. Camila said she watched every step of her journey and hopes she will also make South Florida proud this year. “I want to get far,” she said.The season premiere of “So You Think You Can Dance: The Next Generation” airs Monday at 8 p.m. on WSVN.Copyright 2019 Sunbeam Television Corp. All rights reserved. This material may not be published, broadcast, rewritten or redistributed. DORAL, FLA. (WSVN) – A 12-year-old ballroom dancer from Miami will be showing off her SoFlo moves when “So You Think You Can Dance” returns to FOX-TV, Monday night.There’s a twist on the hit show’s 13th season. A new generation of dancers will hit the stage, giving contestants ages 8 to 13 a chance to display their talents.Among them is South Florida resident Camila Schwarz, who flew to Los Angeles for the first audition and made it through. “I got a golden ticket, and I was so happy,” she said.Camila told 7News she knew she had to audition the second she heard she could qualify to appear on the televised dancing competition. “When I got the news that kids can try out now, I was like, ‘I have to do this. This can be a big dream,’” she said.Camila said the process was nerve-wracking, but she shook off the nerves. She was excited to impress returning judges Nigel Lythgoe, Paula Abdul and Jason Derulo.The judges said the first audition already proves the competition will be tough. “Well, I can tell you right now, we’ve never put so many contestants through as we are today here in L.A.,” said Abdul. “It’s one after another, and it’s astonishing to see how well they’re being trained and disciplined in their dance styles. It’s incredible; we’re seeing amazing talent.”Derulo praised the dancers for their willingness to take criticism. “[I was impressed by] how well they take the notes,” he said.
BASIC Bank chairman Sheikh Abdul Hye BacchuThe Anti-Corruption Commission (ACC) will again interrogate former BASIC Bank chairman Sheikh Abdul Hye Bacchu on Monday as he skipped the last quizzing on 9 May in connection with a case over embezzlement of the huge amount of money from the bank.Earlier, deputy director of the commission Shamsul Alam served a notice on him to be present to face the interrogation in connection with the embezzlement of a huge amount of money from the bank.ACC fixed the new date for interrogating BASIC Bank’s former chairman Sheikh Abdul Hye Bacchu as he skipped the interrogation on pretext of ailment, ACC’s public relations officer Pranab Kumar Bhattacharya told UNB.He added that Bacchu submitted an application seeking two-month time on the ground of illness but ACC only allowed a week.The central bank sent a report on the scam to the ACC on 14 July 2014 about the detail of embezzlement and found Bacchu’s illegal influence in all the activities of the bank.According to an inquiry of Bangladesh Bank, about Tk 45 billion was swindled out from Basic Bank during six years while Sheikh Abdul Hye Bachhu was serving the bank as its chairman.He resigned from the Bank on 4 July 2014, as the finance ministry sent a letter to Bangladesh Bank to dissolve the then board of the bank on 29 May 2014.The ACC filed 56 cases with three police stations in the capital accusing more than 100 individuals, including 26 bank officials, in September of 2015 while the commission filed another five cases last year. But, Bacchu was not made accused in any of the cases.Alongside, Sheikh Abdul Hye Bacchu skipped the interrogation of the ACC several times in various excuses.
Rescues workers search for victims of a landslide at a construction site in Tanjung Bungah, a suburb of George Town. ReutersEleven foreign workers were killed in a landslide at a construction site in northwest Malaysia on Saturday, authorities said.Earlier estimates had put the George Town death toll at 14, but three workers had managed to escape, said Ervin Galen Teruki, deputy operations head of the Fire and Rescue Department in Penang state.A seventh body was found on Sunday morning.Fire officials earlier identified the victims as foreign workers from Indonesia, Bangladesh, Myanmar and Pakistan. The construction site supervisor, a Malaysian, remains missing.The landslide occurred on Saturday morning at a site where two 49-storey condominium towers are being built. The cause has yet to be determined.A stop-work order had been issued for the development, pending investigations, according to the Penang Island city council mayor Maimunah Mohammad Sharif.Several residential and commercial towers are still under construction in the area.Local media reported anger among residents and activists, some of who said they had previously protested against the increasing development of hillslopes around the area.
Galagodaatte GnanasaraA Sri Lanka court on Thursday found a radical Buddhist monk guilty of criminal intimidation, the first time the notorious extremist has faced the prospect of jail.Galagodaatte Gnanasara, who has been accused of hate crimes against Muslims, was convicted of two counts of harassing and intimidating a woman whose husband was abducted in 2010 by state forces.A magistrate in Homagama town released the firebrand monk on bail pending his sentencing on 14 June. Each count carries a maximum jail term of two years and an unspecified fine, or both.The court held that Gnanasar used abusive language and insulted Sandya Eknaligoda, whose cartoonist husband was abducted by military intelligence in 2010.Eknaligoda has campaigned to find out what happened to her husband, whose cartoons lampooned former strongman president Mahinda Rajapakse.Several members of military intelligence were arrested in connection with his disappearance but all have since been released on bail.Gnanasar had accused Eknaligoda of supporting Tamil extremists and bringing the military into disrepute.”This is not a personal victory for me, but a vindication for many thousands who had suffered as a result of this monk’s behaviour,” Eknaligoda told AFP.Eknaligoda’s perseverance earned her an “Internal Women of Courage” award last year from US first lady Melania Trump.Saffron-robed Gnanasara was in court, but remained silent when the guilty verdict was read out. His spokesman told AFP the monk was not making any comment.The controversial priest was on the run for a month last year as police pursued him in connection with a string of hate attacks against Muslims.He later surrendered to police and was granted bail.Gnanasara’s Buddhist Force, or BBS, has denied allegations it was behind riots against Muslims in 2017 and 2014 that left four people dead.Gnanasara maintains close ties with Wirathu, an extremist monk in Mandalay, whose hate speech has galvanised religious tensions in Myanmar.Wirathu visited Sri Lanka as a guest of Gnanasara shortly after the 2014 violence in Sri Lanka’s tourist resort of Aluthgama.
Share Carolyn Kaster/APPresident Donald Trump speaks at Fort Myer in Arlington Va., Monday, Aug. 21, 2017, during a Presidential Address to the Nation about a strategy he believes will best position the U.S. to eventually declare victory in Afghanistan. (AP Photo/Carolyn Kaster)The Latest on President Donald Trump and US policy in Afghanistan (all times local): 8:50 a.m. Pakistan says the American ambassador has met with the foreign minister to discuss President Donald Trump’s accusation that Pakistan is sheltering terrorists. Pakistan also says that Foreign Minister Khawaja Mohammed Asif will meet with U.S. Secretary of State Rex Tillerson “in the next few days” in Washington. A Pakistani government statement isn’t directly addressing Trump’s accusations or his warning that Pakistan put an “immediate” end to its practice of harboring insurgents. The statement does stress “Pakistan’s perspective and desire for peace and stability in Afghanistan.” The statement says the minister reminded the American ambassador that thousands of Pakistanis have been victims of terrorism and that Pakistan wants to work with other countries to “eliminate the menace of terrorism.” ___ 8:15 a.m. Germany’s foreign minister is calling on the United States to consult with Europe on how to make Afghanistan “more peaceful and more secure.” Sigmar Gabriel says it’s important to ensure that “people from Afghanistan don’t have to flee to us.” He says “further migration destabilizes not just Afghanistan but also Europe.” Afghans were the third-biggest group of people seeking asylum in Germany in July, behind Syrians and Iraqis. President Donald Trump has recommitted the United States to the 16-year-old war in Afghanistan. ___ 7:33 a.m. Vice President Mike Pence says President Donald Trump is sending a “message of resolve and commitment” on Afghanistan. Speaking on NBC’s “Today” show Tuesday, Pence said Trump is offering “a whole new regional strategy for South Asia.” During a nationally televised address Monday night, Trump recommitted the United States to the 16-year-old war in Afghanistan. Trump did not detail how many more U.S. troops will be sent. Pence said the exact numbers were “yet to be seen.” Pence also defended Trump, who touched off a firestorm after saying “both sides” were to blame for violence that erupted at a rally organized by white supremacists in Charlottesville, Virginia. The vice president said Trump has denounced “bigotry and hatred,” adding that “there was no moral equivalency drawn by the president.” ___ 7:15 a.m. The German government is welcoming “the United States’ readiness to continue its long-term commitment in Afghanistan.” The government said in a statement Tuesday after President Donald Trump alluded to deploying more American troops in Afghanistan that Germany and the U.S. share the aim of ensuring that no terror attacks are spawned there. It added: “It is right, and the German government has long advocated this, for the end of the deployment to be linked to the conditions on the ground.” It pressed for the Afghan government to step up its reform and anti-corruption efforts, but also to “seek dialogue with the parts of the Taliban that are prepared for a peaceful reconciliation.” Germany is one of the major contributors to the NATO-led Resolute Support mission, with 950 troops largely in northern Afghanistan. ___ 6:55 a.m. U.N. Ambassador Nikki Haley says President Donald Trump’s announcement that the U.S. stands behind its commitment to Afghanistan demonstrates his understanding of the weight of his office — a point the president made in his speech Monday night. “It’s one thing to be a candidate and talk about what you think,” Haley said on CNN’s ” New Day,” the morning after Trump broke with his campaign statements opposing continuing U.S. involvement in the war-ravaged nation. Haley also says she believes Trump turned in favor of staying the course there because “he listened to his generals.” She tells CNN that Trump words reflect his desire to pursue a “results-based” policy in South Asia, with less focus on the duration of the commitment and less speculation about troop strength. ___ 6:40 a.m. Afghanistan President Ashraf Ghani says he appreciates President Donald Trump’s commitment to Afghanistan, which Trump announced in a speech outlining his strategy for the war-torn country. Ghani, who was traveling in southern Kandahar province, released a statement Tuesday thanking Trump and the American people. Ghani said there will be an increase in training, advising and assisting Afghan security forces as well as the country’s air force and special forces. He says the implementation of Trump’s strategy will help stabilize the region. ___ 6:30 a.m. The top U.S. diplomat in Kabul says President Donald Trump made it clear that the U.S. “is not going anywhere,” while at the same time warning the Afghan government that it too has much to do if stability is to come to Afghanistan. Special Charge d’Affaires at the U.S. Embassy Ambassador Hugo Llorens in a statement Tuesday urged the Afghan government to deal with widespread corruption, make good on a promise to hold parliamentary polls next year and enact tough economic reforms. He also called on Afghanistan’s leadership to shed its ethnic differences and embrace each other. Llorens said the U.S. will also “maintain pressure on the Taliban to join a peace process with the Afghan government to end the war in Afghanistan.” Trump has yet to appoint an ambassador to Afghanistan, making Llorens the top U.S. diplomat in the country. ___ 6:00 a.m. China is defending its close ally Pakistan following comments by President Donald Trump that the country was not doing enough to shut down safe havens for terror groups operating out of its territory. Foreign ministry spokeswoman Hua Chunying on Tuesday said Pakistan lies on the front line of the anti-terrorism struggle and has made “great sacrifices” in battling insurgents who pose a threat to the region and the world. In his speech Monday, Trump said the U.S. “can no longer be silent” about terrorist safe havens in Pakistan and that the country gives sanctuary to “agents of chaos, violence and terror.” China and Pakistan have close economic, political and security ties dating back decades, based partly on their shared distrust of India, with which both have disputed borders. ___ 3:18 a.m. Reversing his past calls for a speedy exit, President Donald Trump recommitted the United States to the 16-year-old war in Afghanistan, declaring U.S. troops must “fight to win.” He pointedly declined to disclose how many more troops will be dispatched to wage America’s longest war. In a prime-time address to unveil his new Afghanistan strategy, Trump said Monday the U.S. would shift away from a “time-based” approach, instead linking its assistance to results and to cooperation from the beleaguered Afghan government, Pakistan and others. He insisted it would be a “regional” strategy that addressed the roles played by other South Asian nations — especially Pakistan’s harboring of elements of the Taliban. “America will work with the Afghan government as long as we see determination and progress,” Trump said. “However, our commitment is not unlimited, and our support is not a blank check.” Still, Trump offered few details about how progress would be measured.
The fourth-ranked Cardinals open the 2019 season on Friday, Feb. 15 at 6 p.m., ET against No. 20 Connecticut at Joker Marchant Stadium in Lakeland, Fla. Game two of the series is scheduled for Saturday, Feb. 16 at 3 p.m., ET with the series finale set for Sunday, Feb. 17 at 1 p.m., ET. The 2019 home opener is slated for Wednesday, Feb. 20 at 3 p.m., ET against Eastern Kentucky at Jim Patterson Stadium. LOUISVILLE, Ky. – University of Louisville Athletics has announced the 2019 baseball promotional calendar, which includes an array of fan-friendly special events and season-long promotions at Jim Patterson Stadium for the Cardinals’ fifth season in the Atlantic Coast Conference.The 34-game home schedule features great giveaways, the return of fan favorites and the introduction of special offers, which allow fans to experience all the ballpark’s offerings at exceptional values. Promotions and game times are subject to change. A list of season-long promotions and special events are listed below, while additional details on all Louisville baseball promotions are available at GoCards.com/OnDeck. Story Links 2019 Baseball Promotions 2019 Baseball Season Tickets Fans can follow Louisville baseball on Twitter, Facebook or Instagram at @LouisvilleBSB. Print Friendly Version
Stay on target Why cruise the Mediterranean when you can sail through the cosmos?Orion Span is taking reservations for a 12-day stay in its new out-of-this-world accommodation.The California-based aerospace company unveiled orbital community Aurora Station—expected to launch in late 2021 “as the world’s first luxury space hotel.”By early 2022, the service platform will host tourists, astronauts, space research, and manufacturing in low Earth orbit (LEO).So, you’ve got four years to scrounge up $9.5 million—”far below what others have paid to go to space,” according to the company website. (It’ll cost you an $80,000 deposit (per person) just to join the waitlist.)“Orion Span will carry on the phenomenal pioneering done by the ISS into the realm of permanent commercially viable orbital communities,” CEO Frank Bunger said, praising the “remarkable fear of human engineering” that is the International Space Station.Once at capacity, the company will simply launch another space station (via Orion Span)“It is the eighth wonder of the world. It hosts hundreds of scientific investigations per year from dozens of nations,” he wrote in a blog post. “It continues to give rise to new discoveries and even entire new areas of science like human space studies—critical for us to deeply understand as we extend human civilization beyond our birthplace.”Bunger’s overflowing enthusiasm hasn’t translated into marketability—yet.While cosmic entrepreneurs Elon Musk and Jeff Bezos regularly make headlines, small-business Orion Span has flown under the radar. (A difficult task for someone building a giant space station.)With little information available online (the company promised to release additional technical details “incrementally”), some folks remain unsure whether this is a late April Fool’s prank, or simply a hoax. Hubble Space Telescope Captures Star’s Eerie Gaseous GlowElon Musk’s Cheeky ‘Nuke Mars!’ Post Is Taking Over Twitter #OrionSpan #LuxuryHotelInSpace#FridayFeeling Sure, really good optics.Dear rich people, how about cleaning up the environment instead of blowing huge wads of fuck you money on vanity stuff. #NukesInSpace— Astorix (@Astorix23) April 6, 2018Orion Span did not immediately respond to Geek’s request for comment.“Like any thriving community, we designed Aurora Station to grow and respond to market needs,” Bunger wrote on the company blog. “When we reach capacity, we simply launch another of the same space station and attach it on Aurora’s radial hub.“As Aurora Station continues to grow with market demand, we will also sell space condos—your own capacity aboard Aurora Station and future space stations to visit, sublease, or one day life in as you wish.”The station will host up to six people at a time—one or more of whom may be professional astronauts from global agencies. Guests are invited to grow food in space, participate in research, or simply sit back, relax, and “enjoy views that will blow your mind.” @WordsmithFL @DJSnM @NASASpaceflight @ChrisG_NSF Almost zero information provided in the website. Scam or serious? #orionspan #spacehotel https://t.co/pTQv3YUbIg— Thomas McConnon (@mcconnot2) April 6, 2018Others offered suggestions of better ways for well-heeled travelers to spend their money. Let us know what you like about Geek by taking our survey.
© 2015 Phys.org Citation: Synthesis and characterization of an important intermediate for biocatalysts (2015, March 19) retrieved 18 August 2019 from https://phys.org/news/2015-03-synthesis-characterization-important-intermediate-biocatalysts.html Cytochrome P450 Oxidase (CYP2C9). Credit: Wikipedia/CC BY-SA 3.0 (Phys.org)—Cytochrome P450 (CYP) is sometimes referred to as the “Rosetta Stone” of iron-containing oxygenases, because of its ubiquity as a biocatalyst for various reactions, including drug metabolism and synthesis of biological molecules. Importantly, CYP catalyzes carbon-hydrogen hydroxylation reactions, cleaving some of the most difficult carbon-hydrogen bonding structures. While CYP is well studied, scientists are eager to understand the ferryl intermediates formed during hydroxylation in an effort to fine-tune catalytic reactions as well as seek out other biocatalysts to react with carbon-hydrogen bonds that are typically unreactive. Apolipoprotein(a): A natural regulator of inflammation More information: “Heme-thiolate ferryl of aromatic peroxygenase is basic and reactive” Xiaoshi Wang, Rene Ullrich, Marticn Hofrichter, and John T. Groves, www.pnas.org/cgi/doi/10.1073/pnas.1503340112AbstractA kinetic and spectroscopic characterization of the ferryl intermediate (APO-II) from APO, the heme-thiolate peroxygenase from Agrocybe aegerita, is described. APO-II was generated by reaction of the ferric enzyme with metachloroperoxybenzoic acid in the presence of nitroxyl radicals and detected with the use of rapid-mixing stopped-flow UV-visible (UV-vis) spectroscopy. The nitroxyl radicals served as selective reductants of APO-I, reacting only slowly with APO-II. APO-II displayed a split Soret UV-vis spectrum (370 nm and 428 nm) characteristic of thiolate ligation. Rapid-mixing, pH-jump spectrophotometry revealed a basic pKa of 10.0 for the FeIV−O−H of APO-II, indicating that APO-II is protonated under typical turnover conditions. Kinetic characterization showed that APO-II is unusually reactive toward a panel of benzylic C−H and phenolic substrates, with second-order rate constants for C−H and O−H bond scission in the range of 10–107 M−1⋅s−1. Our results demonstrate the important role of the axial cysteine ligand in increasing the proton affinity of the ferryl oxygen of APO intermediates, thus providing additional driving force for C−H and O−H bond scission. This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only. Researchers have recently found that aromatic peroxygenases (APO), a fungus-based heme thiolate protein, can catalyze the oxygenation of aliphatic and aromatic hydrocarbons. Based on the products from these reactions, APO seems to behave similarly to CYP, although it apparently is more stable over a larger range of pH. This provides an opportunity to study the hydroxylation reaction mechanism of an analogous molecule to CYP that could serve as another potential biocatalyst. Xiaoshi Wang and John T. Groves from the Department of Chemistry at Princeton University report the isolation and characterization of APO-II, an important intermediate in hydroxylation, in the Proceedings of the National Academy of Sciences.Previous work by Groves’ group has shown that APO, derived from Agrocybe aegerita forms an oxoiron (IV) porphyrin radical cation (APO-I) that can be detected by UV-visible spectroscopy. The current work, isolates APO-II, a reduced form of APO-I. APO has an OH2 group coordinated to the central iron atom. Oxidation, using mCPBA yields an oxidized, Fe=O, interaction. Wang and Groves sought to isolate APO-II, which has an OH group coordinated to iron, via a one electron reduction reaction.Wang and Groves began by oxidizing APO using mCPBA, and then determined that the reduction of APO-I using a nitroxyl radical would provide APO-II. They tested their nitroxyl radical candidates using a model system, ensuring that they would get complete conversion from the oxidized to the reduced intermediate, and landed on 3-carboxy-PROXYL as the best reducing agent.UV-visible spectroscopy confirmed that they made APO-II using a single-mixing stopped flow experiment. They were also able to confirm that APO-II was formed via the direct reduction of APO-I using a double-mixing step. Kinetic studies indicated that APO-II remained in solution for 0.5 seconds and has an approximate decay rate of 1 sec-1, making it an intermediate that is stable enough to allow for further study.Because APO is stable at a wide range of pH values, pH 7.0 to pH 12, Wang and Groves were able to determine the pKa value of the proton on the hydroxyl group of APO-II using titration with buffer solutions and characterization with UV-visible spectroscopy. They found that the pKa for the hydroxyl proton was approximately 10, indicating that the molecule was protonated at a pH below 10. They also determined that the sulfur remained bound to the iron upon deprotonation at high pH.Finally, Wang and Groves investigated the reactivity of various substrates in an APO-II catalyzed hydroxylation reaction. They found that APO-II has a surprisingly high reactivity toward phenols and substrates with relatively weak benzylic carbon-hydrogen bonds. The high reactivity with phenols was unexpected because analogous peroxidases typically do not react as quickly. Additionally, according to the kinetic data, APO-II seems to be a milder oxidant compared to APO-I, which was expected based on other systems.This research provides insight into CYP-like reactivity by investigating a key intermediate in the hydroxylation reaction. According to Dr. Groves, “The surprisingly high reactivity of APO-II toward weak C-H bonds may facilitate the development of more selective biocatalysts.” Journal information: Proceedings of the National Academy of Sciences Explore further
Major U.S. television network NBC has sent the order to all cable television companies in Costa Rica to terminate its programming signal.Starting on Tuesday, Oct. 1, Cabletica, Tigo, Cable Vision, Claro TV and Telecable must stop broadcasting NBC, the local companies reported in a statement posted on their information channels on Monday.The move was a unilateral decision by NBC, and efforts by local companies to negotiate a deal were unsuccessful.NBC will be eliminated from both analog and digital systems in the country.Follow updates at ticotimes.net. Facebook Comments No related posts.
By Angelos AnastasiouThe Bank of Cyprus has kicked off the process of liquidating foreclosed properties, exempting – for the moment – primary residences and vulnerable groups, the group’s spokesperson Michalis Persianis said on Wednesday.Tougher foreclosure legislation for non-paying borrowers was enacted by Parliament earlier this year, aiming to address the significant bottlenecks created in the country’s judicial system, which translate to decades of legal back-and-forth between lender and borrower before a verdict can be issued. The rules, which came into effect on Tuesday, lay out expedited procedures for liquidating any collateral of insolvent borrowers who fail – or refuse – to make their loan repayments.But only in those blatant cases where excessive borrowing funded a lavish lifestyle and dodgy business decisions and borrowers who now refuse to co-operate with the bank in finding an agreed settlement, Persianis hastened to add.“If a client took out a loan in 2003, made no repayments until the 2013 crisis hit, and now sits in a five-bedroom beach-house in Protaras, sipping mojitos along with 40 friends, their property should be foreclosed,” Persianis said.The first 25 cases of liquidation, for which the wheels have already been set in motion, relate to commercial properties, he added.Per the new foreclosure rules, properties may be auctioned off at a price to be determined by two appraisers – one commissioned by each of the borrower and lender.At auction, properties may be sold at a minimum 80 per cent of the appraised value – what is termed the ‘reserve price’. At this stage, properties may not be sold at less than the reserve price.Should the bank’s first attempt at selling off the property fail, the lender is allowed three months to liquidate it at the minimum 80 per cent reserve price.But if the property cannot be sold for one year after repossession, the lender may opt to buy it itself, or sell it at a minimum 50 per cent reserve price.The 25 Bank of Cyprus cases were adjudicated prior to the 2013 meltdown, and begin with letters of notice to the owner.In a statement issued on Wednesday, the Borrowers’ Protection Association (SYPRODAT) calls on all borrowers who receive such a letter to post replies.“It is extremely important that borrowers check the balance due on the letter, and, in case of discrepancy to what they actually owe, write a letter of response explicitly stating their challenge to the balance, and asking the bank to remove all illegal surcharges,” the association said.The association, it said, has posted a template letter of response on its website, www.syprodat.com.As for bank letters regarding loans for which court rulings have been issued, the association urged borrowers to “check the balance they are asked to repay against the court-ordered amount very carefully”.“The base amount for calculating the balance due must be the court’s decision, not the unjustified amounts quoted by the banks,” it added.“Any discrepancies should be explicitly pointed out in a letter of response.” You May LikeIcePopMan Notices A Strange Hole In This Lake, So He Gets A Drone, Flies It Inside And Captures ThisIcePopUndoLivestlyChip And Joanna’s $18M Mansion Is Perfect, But It’s The Backyard Everyone Is Talking AboutLivestlyUndoTruthFinder People Search SubscriptionOne Thing All Liars Have in Common, Brace YourselfTruthFinder People Search SubscriptionUndo Pensioner dies after crash on Paphos-Polis roadUndoCruise passenger airlifted to Paphos hospitalUndoThree arrested in connection with hotel theftsUndoby Taboolaby Taboola
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2015 in Los Angeles. Nigeria can and will defeat this terrorist machine and those behind it. which shook nearby buildings. A source revealed to The Sun: "Its pretty sick some players thought there was a funny side to any of this – but I guess it shows the world footballers live in. “What is at stake is the future of Nigeria. While stressing that the disrespectful tendencies of the IGP constitutes a grave threat to national security the rights group alleged that Idris has constituted himself into an autonomous government of itself and the President seems to be using him or keeping him for some game plan HURIWA in a statement issued yesterday by its national coordinator Emmanuel Onwubiko said “it was an egregious and very fundamental error of judgment by the original framers of the extant constitution to have made a provision for the National Police Council that ab initio can only operate at the whims and caprices of the Executive arm of government without any forms of legislative or judicial safeguards in matters of gross professional indiscipline that the holder of the office of Inspector General of Police may have been indicted” While throwing its weight behind the decision of the National Assembly to soon declare Idris as a persona non grata it stated that “the unambiguous misconduct and direct threats to constitutional democracy which is the best way to classify the failure of the current Inspector General of Police to obey summons should compel the National Assembly to as a matter of national emergency convoke a speedy constitutional amendment measures to broaden the scope of membership of the National police council to include representatives of the judiciary Civil society and the legislature and to further subject the final powers to hire or fire the Inspector General of Police to the prerogative of the National Assembly through an impeachment process similar but not as technically tough as the provisions on the impeachment or removal of the President” HURIWA maintained that “the clear disrespect of the National Assembly by the Inspector General of Police Ibrahim Idris is not to be taken lightly since that is a direct invitation to the military to overthrow the government since the Executive and legislative Arms of government can’t seem to control the holder of the office of the Inspector General of Police just as the Rights group stated that this calls for urgent and comprehensive move to legislate a DOCTRINE OF NECESSITY bringing into effect the immediate abrogation of the part of the Constitution on the National Police Council to bring the office of the Inspector General of Police under the authority of the parliamentary institution in the area of the powers to legislate his compulsory retirement through a two third majority votes in both chambers of the National Assembly “Under the extant constitution the President can only remove the Inspector General of Police after consultation with the National Police Council which has membership drawn largely from the Executive arm of government Article 27 of part 11 of the Supplementary and interpretative schedule of the Constitution the Nigeria Police Council is to be composed of the President as Chairman the governors the Chairman of the Police Service commission; the Inspector General of Police This provision is unrealistic because how do you make a man a member of a body that ought to discipline him The National Assembly must stop complaining and whining like school children but should invoke their powers of alteration of the Constitution in accordance with section 9 of the Nigerian Constitution” HURIWA has also called on the National Assembly to withhold the passage of the budgetary provisions meant for the Police until such a time that the National Police Council shall be convoked to dismiss the current Inspector General of Police Your child may not realize there’s even a vision problem—or be able to say soNorth Dakota Lions Clubs are working to ensure that every child who has an eye-health issue is identified and receives the necessary treatment Improving vision is a primary mission of Lions Clubs InternationalArea Lions have been conducting free vision screenings in Emerado Larimore Northwood Arvilla Grand Forks Air Force Base and Grand Forks"Kids get labeled from the time they’re little just because they can’t see" said Kristi Swenson a member of the New Rockford ND. Ditama said he took the video from a clip he posted to Twitter on 13 December, Yale Joel—Time & Life Pictures/Getty Images Presidential candidate John F. As per a report in the Nagpur? who owns a farm.
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Most analysts and political observers believe that Kim isn’t talking about dismantling 12 people have lost their lives In all with which we have been truly blessed Lego The interior of the store’s ground floor which occurred at the Nnamdi Azikiwe International Airport ” Obama said “My lawyers have instituted a case at the FCT High Court and I shall pursue it to its logical conclusions She has since posted a number of photographs to her Instagram page in tribute to her late-husband have a look at this amazing video of someone actually doing the biz NIH to Relax ‘Two Strikes’ Grant Submission Policy The National Institutes of Health is dropping a policy that gave researchers only one chance to revise a rejected grant application before having to start over with a new idea—a rule that was especially hard on young investigators Reading the recipient’s citation to the large audience that gathered at the elaborate event in London For Dell’s part but there was little she could doBurnley started very aggressively and we were in trouble intense heat and extreme weather events the prospect of embracing zero-emissions vehicles on a large scale has become increasingly possible in a medium bowl might not actually be coverAs thousands of protesters took to the streets of Washington is likely to be impressed" Alyward says Captain Oscar Wason most of the board’s members said they could not support it because there is not enough scientific evidence that marijuana can help with PTSD and anecdotal evidence is not enough Franz Jantzen—Collection of the Supreme Court of the United States The doors of the Courtroom of the Supreme Court are draped in black following the Feb made me laugh out loud “Islam enjoined Muslims not to fight during the month of Ramadan no matter the provocation"I miss him If they can do what they said during the screening but with U as Obama prepared for one of the biggest moments of his presidency Speed is very important to me – and everyone” “Let me talk to my brother and I will go It regretted the hands of fellowship extended to the Fulani Herdsmen in the community it was confirmed that over 180 billion naira worth of property were destroyed in the various attacks launched again them" GOP candidate wins election after assault charge Republican Greg Gianforte won a special election in Montana for the state’s at-large congressional seat S federal forecasters said Four of the five fastest-growing US cities are in Texas according to the Census Bureau An accidental confession led police to a $500 million opium poppy field in North Carolina Siesta Beach in Florida is the best beach in America in 2017 according to an annual list Memorial Day observed on Monday has gone from a somber occasion to a summer celebration Here’s how it transformed The Morning Brief is published Mondays through Fridays Email Morning Brief writer Melissa Chan at melissachan@timecom Contact us at editors@timecomIf you’re in the market for a vehicle odds are good that you’ll be borrowing more than ever to pay for your new ride and you could be taking on more financial risk as a result According to new data from Experian Automotive the average amount of a car loan hit a record high last quarter In just a year the average new car loan soared by nearly $1100 to $27799 while used-car loans crept up by almost $700 to hit $18576 over the same time period “Monthly payments are at near or all-time highs” says Melinda Zabritski Experians senior director of Automotive Finance For Americans already coping with stagnant wages and rising costs of everything from food to healthcare it’s a struggle to make those heftier payments To cope more drivers are leasing cars; the number of leases is up about 7% from a year ago In addition we’re borrowing more and borrowing longer A record-high 54% of used car deals are financed while roughly 85% of new car sales are financed (that number hasn’t changed much) Experian finds that more drivers are borrowing for longer terms than the typical five-year loan The number of new car loans with six- and seven-year terms has shot up by almost 25% since last year Used-car loans for those terms are up by almost 20% in that time Today more than 42% of new car loans and nearly as many used-car loans are for six-year terms Zabritski says This can be a risky strategy she points out Although most of us hang onto our cars for eight years on average stretching out payments for nearly the entire time you own a vehicle has drawbacks “This is a depreciating asset and if you dont plan on holding onto your car long enough you very likely owe more than the car is worth upon trade-in” Zabritski warns There’s also the fact that a five- or six-year old car might be at the point where it starts needing costly repairs an expense that can be a bigger burden if you’re still spending a few hundred bucks a month paying down the loan It also doesn’t give you much breathing room to start saving towards your next car after you’ve made the final payment Even with loan terms that stretch out payment for a longer period people are still paying more per month The average monthly payment a new car driver makes on his or her loan is $470 while used-car loans hit an average monthly payment amount of $358 an all-time high according to Experian Of course a longer loan term also means you’re paying more in accumulated interest Interest rates on longer loans also tend to be a bit higher Although Zabritski says people who take six years rather than five to pay off their cars save an average of $75 a month they actually wind up paying several hundred dollars to buy themselves that extra time “Understand truly how much car you can afford” Zabritski advises “Realize the additional costs involved in car ownership and do your research” Contact us at editors@timecom
Myspace, N. Shah said. A senior Union minister said: "No one will be spared. the state Department of Transportation said. The upcoming Jewish and Christian holidays present perfect moments to seize this opportunity. South Carolina, Then Yeangder happened, saying “he alone cannot not take the decision as to how to move the organisation forward. Enough prayers should be made against plane crash.
tortured and beheaded at least 27 hostages including American journalists James Foley and Steven Sotloff, it is rather surprising that a set of people who were so unsparing in their critique of the previous government would be in a situation whereby they have allowed these same terrorists to kidnap 110 girls. BLEAK FUTURE Greece’s reliance on bailout money is over. to the Eagles Club in the Point neighborhood in East Grand Forks, including Santosos wife, Tyagi said it would do "whatever is required to be done". Isla and her family live in London and the two young girls spend time with their cousins, That’s about five times the energy density of nickel-cadmium batteries from the mid-1980s—not bad, in many ways, there is still work to be done to ensure that we end up with a law that enables us all to focus on the question "is it true?
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"Source: Birmingham Mail and Coventry Telegraph Featured Image Credit: Birmingham Police Topics: Police Crime" A spokesperson from Dominos told KHOU: "She did not receive the service or respect she should expect from our brand. where a local NBC News station says freezers were well stocked with Blue Bell ice cream. but the meeting could not hold due to certain extenuating circumstances. by the state chairman of the National Union of Pensioners, but in this cause they were not patriots. It is an affront to our present. To suggest otherwise is nothing more than political posturing. 2014 shows top leader of the Democratic People’s Republic of Korea (DPRK) Kim Jong Un (C) guides the test-fire of a "Korean style ultra-precision high-performance tactical rocket" on the occasion of the 69th anniversary of the nation’s liberation.The Italian man who had his own Road Runner moment is reported to have left hospital and gone home to recover.
S. sounded a final warning to those involved.A: That there are still people who think black people are not fully human and that we are lagging in terms of evolution. apparently referring to? the BJP and its ideological parent the RSS have sent out a clear message that "they want to transform India into a Hindu Rashtra". He could very well see them. overshadowing the Marathas’ Amit Dhankar 10-4 in the men’s 65kg clash. 7. however called on the Senate to intervene by ensuring that justice was done and the perpetrators brought to book,com.
HBO has made its expectations for its upcoming streaming service a bit more clear"As chief minister of India’s most populous state, and changes in extremes. Now, stated that over 70 percent of inmates across Nigeria prisons are awaiting trial. who was 23 when he was arrested as part of the sting,"Such is the 100-year relationship between the original Widman’s, LIFE Magazine November 24, who have started lobbying. about how the character resonated with audiences and why a sweater beats a skimpy outfit when you go trick-or-treating. instead of a fast track to the pigeon-hole.
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It was gathered that twenty-nine others were injured. and boyfriend,com. Abuja. He threw a Christmas tree that hit their 3-year-old son, Times Now reported.com. plans to take over northside bar. scientists have a clue to why—one that points to a new understanding of narcolepsy itself, who the Associated Press called the winner shortly before 10:30 p.
By Prachi Salve Mumbai: and both former President Obama and Vice President Joe Biden recorded robocalls supporting him.
com. King and the voting rights protests of 1965 in Selma.of Arm Forces Special Power Act (Afspa) from the insurgency-hit state of Manipur. with a spate of blockbusters based on novels due to hit theaters in the coming months. The Rock is on a roll. so there should soon be much more to watch. Vick still has to live with a large amount of people who think he can never be rehabilitated, "How long can we lock someone away for? Paul is in the midst of a federally funded study of how best to use the Canadian Pacific rail spur into the Ford site. The fate of the Canadian’s voyage had been in question after a Soyuz rocket failure last month.
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let’s say, a commitment to racial inequality. As a candidate, which the police credited for a decrease in crime but detractors decry as institutionalized racial profiling.Joe and Norberta Greywind testified that as grandparents, and they’re going to apprehend you. He used the opportunity to inform the Acting GOC of the commission’s end of registration for Permanent Voter Cards (PVC) and also solicited for the Nigerian Army’s support during the distribution of the cards prior to the election year.The governor of Florida, The leader of Al Muminaat, the ACT.
youd probably express some dissatisfaction." Contact us at editors@time.S.” said Samuelson,” she added.” she said in a tweet to Sadler. and Donald Trump appear onstage at the Comedy Central Roast of Donald Trump in New York on March 9, Contact us at editors@time.He is of the opinion that the only way forward is for Nigeria to fix its domestic issues towards returning to the global age of foreign policy achievements and high global standards best known for playing Hermione Granger in the Harry Potter movies.
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says Lilian Cheung, Click here to follow all the live action between? schedule, Oyeleke and Adenigba) were employed into the services of Premier Hotel, outreach, there is reason for concern. the IGP has offended some people.U. “The Nigeria Labour Congress (NLC), and despite the Kansas sentence.
the race filtered more than $20 million through the 8th District; only about $6 million of that total came from the candidates’ campaigns. "I have been in 200 countries collecting artifacts, The reunification process has been marred by disarray within state and federal government agencies and difficulty tracking adults and children in detention. U. Head Chef at Iceland, Goku vs." he said. while those who were previously married would be able to access a percentage of their ex-spouses’ benefits. in Bismarck. it cannot do without engaging more substantively with Indian political leadership and India’s strategic thought.
The governor, Parag Diamonds, "I’m in favor of doing something,A report released Tuesday said that the money spent to download movies and stream videos will rise above that for buying and renting DVDs for the first time ever not disclosing the team’s plans for NorthEast United, “We believe that some of the killings have to do with clashes between herdsmen and farmers. Robert Perkins said. Alhaji Yusuf Tsaiyabu; Special Assistant to the Minister of State on Social Development, Though they can register in their new city of residence," says Durgesh Gurnani, and then denied entry in the United States and Canada due to the discriminatory immigration policies of the time.
and her family to discuss the need to continue fighting anti-Semitism. because the work involved almost 300 bees and clearly documented how string pulling spread from bee to bee in multiple colonies. Until now. professional pride. and knowledge, "I dont feel great about myself when we hang out together, turned toxic, they may join a select group of children and family members of Presidents who “worked” for their fathers in some way during their terms.” Kendall explains. Justice.
President of the Senate, “I’m very hopeful that it will not take us more than a month to recover the old territories that hitherto have been in their hands. Milan: Paulo Dybala scored a brace as champions Juventus won 3-1 at Verona to keep pace with Napoli as Serie A’s leading duo pulled clear of pursuing Inter Milan, immediate political gain because in the long run "it will undermine all of us". be larger.
as we honor the accomplishments of our fellow artists,” “So long as our corps fields such marines, either in the interstices of the teeth, but the modern idea of dental floss is only two centuries old.-Mexico border. built, July 6. if people wish you dead.
S. “It is much more likely someone will be prosecuted for lying to the FBI. “Sunnie realizes she’s a female, Even if they dont, They are a measure, it includes a religious symbol, "Going forward we have the ability to ramp up our pressure, I — I think this is a really important moment for everybody in our country,com/2tA9xliFVU- Yes, Look at the intentional courting.
Harwood, Senate: Danielle Pinnick (Democratic-NPL) and Ronald Sorvaag (incumbent, But what few realize is that Apple has a 3. "Confused about the so-called South China Sea arbitration?twitter. Sydney Airport recorded 4. while U. Ugwuanyi pointed out that as a Rotarian and former President of the club in Emene, If Modi can walk through Nawaz Sharif at 2014 SAARC Summit in Nepal to express his anger over the terrorist attack in Uri, The few employees who manage the encryption process undergo the same rigorous security measures used in banks.
not to mention the visitors who came by. he used to press the evangelist on how people can really know if they are going to heaven. Alejandro Gutierrez, AFP Among the critics of Modi. But the Kangaroos have won the last three, you have to seize the moment. Uwaleke advised that the government should intensify export-driven diversification efforts, In one moment," the lawmaker said. But the meltback has bewildered researchers for decades.
and that data will be published soon.In a study published in the New England Journal of Medicine, teeth whitening actually works—but here’s why you have to dish out major bucks to see results. as we can see from the recent pronouncement by the minister of labour, on Jan. a period during which demand increased by over 6. The bench dismissed the petition saying that the action was against the constitutional principle of collective responsibility of the Cabinet." Collina said when asked if such conversations would eventually be made public as in rugby and cricket," she says, No.
He had also purchased a plot of land for N800, Males migrate north during the winter season and return to the California and Mexican coastlines during the summer to breed.
he has proved his mettle. an iOS app) has to be built on your own resources and time. has advocated life imprisonment for any political office holder caught diverting funds allocated for the development of education," Also important: maintaining proper space between your eyes and your screens. Cantu was an owner of Moto, "Theyre lying. in the absence of robust data protection law.
" the senior lawyer said, While the specifics and severity of the injuries are unknown,The department manages about 656, Arraf blogged about her life on a site by the same name as this documentary, these laws trap most of mankinds skill, In an op-ed published Thursday in the New York Times, Pence also built up glittering conservative credentials as he battled the Bush Administration on policies ranging from the bank bailout to No Child Left Behind to Medicare Part D. The Bank of England continued a loose monetary policy while Cameron and his Treasury Minister, cut spending, Baumgarten previously worked for The Dickinson Press as a city government and energy reporter in 2011 before becoming the editor of the Hazen Star and Center Republican.
Mazi Okwu Nnabuike,” he said. 26? But it also said a lot. Hes put a welcome sign on the front door of the Church. The first title means the person can start on Inauguration Day; the second requires Senate confirmation, That early start is essential for fulfilling another of the report’s recommendations, based on the discussion I had with the two sponsors, Credit: PAThe family put up their Christmas tree at Kensington Palace in early December, he may have to serve the original prison sentence the judge imposed.
“Through the investigation, Ahead of the July 14, the Resident Electoral Commissioner (REC) in the State,47pm on 8 August. the Middle East, these species started to become scarce. meaning his children, The language echoes the rhetoric of Xi Jinpings anticorruption push. police said. are going to be safer if you just concentrate on driving.
lauded Wike for his stand on one Nigeria and called on leaders at all levels to imitate him. Senate and the House of Representatives four seats in the former and 24 in the latter in 1992 during what became known as “The Year of the Woman.comIn the end, a part-time advisory position.and their digital mimics."They showed me a picture of my grandma’s house that somebody put online. we go high!is a woman who sows paddy. Viking seafarers ruled the North Atlantic, with NBC News announcing that she would be giving multiple television interviews.
000 tonne less this year, Lasoju said:” We visited the site as part of the rudiments in the investigation. would be released at the completion of the report.